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电池原位红外附件

电池原位红外附件

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电化学原位红外光谱分析是红外分析技术的一个重要分支,能够定性分析电催化(如CO2电还原等)反应、各种类型电池(如锂离子、锂硫电池等)充放电过程中电极表面的产物或中间产物随时间(电位)不断变化的趋势,是研究电化学反应机理以及电化学反应动力学的重要手段之一。

构造原理

(1)两电极体系,专为电池体系设计。

(2)电化学反应池气密性良好,可通入反应气体。

(3)金刚石晶体,适用性广。

屏幕截图 2023-08-01 164839.jpg屏幕截图 2023-08-01 165014.jpg

图2:基本原理示意图

 

附件组成

(1)红外光谱仪主机适配底板,适配主流红外光谱仪。

(2)光路系统。

(3)PEEK材质气密性电化学池。

(4)O型圈密封件。

 

主要特点

(1)优化的光路系统,光通量大。

(2)电化学池密封性能好,可通入反应气体。

(3)金刚石晶体光通量大。

(4)独特的电极,电解液信号采集调节技术。

(5)可实现电化学红外质谱三联用。

(6)金刚石晶体板和电化学池拆卸方便,可方便在手套箱中组装电池。

(7)提供现场技术服务。

 

主要技术参数

1.光谱范围:250/525-4000 cm-1

2.晶体种类:金刚石晶体

3.电化学池:PEEK材质,两电极体系,气密性池体,可方便在手套箱中装卸电池,设有进气口和出气口,可实现各类电池充放电过程中红外光谱的采集。

4.温控电化学池,温控范围:RT-100℃,温控精度0.1℃。

5.电极与金刚石晶体距离调节系统,带刻度微调功能,重现性好,以实现观测电解液溶剂化或电极表面物种变化。

6.电化学池可实现电化学质谱仪与红外三联用,提供多联用技术方案。

7.反射次数:单次反射。

8.反射类型:外反射。

9.光路反射系统适配主流品牌红外光谱仪,提供光谱仪适配底板,光路系统方便安放或取出光谱仪样品仓。




应用案例


红外电池中图.jpg

锂离子电池 Chem. Mater. 2020, 32, 8, 3405–3413



图片3.jpg

锂离子电池 ACS Energy Lett. 2020, 5, 1022−1031



图片2.jpg

锌离子电池 Adv. Funct. Mater. 2020, 2003890



图片1.jpg

锂离子电池  Joule 2022, 6, 399–417


部分客户论文发表清单:

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  6. Xinwei Ding, Zhi Yang*, et al. Biomimetic Molecule Catalysts to Promote the Conversion of Polysulfides for Advanced Lithium–Sulfur Batteries Adv. Funct. Mater. 2020, 30, 2003354 

  7. Hong Guo*, Xueliang Sun*, et al. Dual Active Site of the Azo and Carbonyl-Modified Covalent Organic Framework for High-Performance Li Storage. ACS Energy Lett. 2020, 5, 1022-1031

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  9. Suya Zhou, Zhi Yang*, et al. Dual-Regulation Strategy to Improve Anchoring and Conversion of Polysulfides in Lithium–Sulfur Batteries ACS Nano. 2020, 14, 7538–7551

  10. Yongyao Xia*, et al. Low-Temperature Charge/Discharge of Rechargeable Battery Realized by Intercalation Pseudocapacitive Behavior. Adv. Sci. 2020, 7, 2000196

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  13. Huani Li, Shubiao Xia*, Hong Guo*, et al. Red Phosphorus Confined in Hierarchical Hollow Surface-Modified Co9S8 for Enhanced Sodium Storage. Sustainable Energy Fuels. 2020, 4, 2208-2219 

  14. Guanglei Cui*, Liquan Chen, et al. Non-flammable nitrile deep eutectic electrolyte enables high voltage lithium metal batteries. Chem. Mater. 2020, 32, 3405-3413 

  15. Guanglei Cui*, et al. Investigation on the Cathodic Interfacial Stability of Nitrile Electrolyte and its performance with High Voltage LiCoO2 Chem. Commun. 2020, 56, 4998-5001 

  16. Zhongbin Zhuang*, et al. A highly-active, stable and low-cost platinum-free anode catalyst based on RuNi for hydroxide exchange membrane fuel cells. Nat. Commun. 2020, 11, 5651 

  17. Tiancun Liu, Yong Wang*, et al. Organic supramolecular protective layer with rearranged and defensive Li deposition for stable and dendrite-free lithium metal anode. Energy Storage Materials. 2020, 32, 261–271

  18. X. Yin, Y. Wang*, et al. Designing cobalt-based coordination polymers for high-performance sodium and lithium storage: from controllable synthesis to mechanism detection. Materials Today Energy. 2020, 17, 100478

  19. Song Chen, Jintao Zhang*, et al. Regulation of Lamellar Structure of Vanadium Oxide via Polyaniline Intercalation for High-Performance Aqueous Zinc-Ion Battery. Adv. Funct. Mater. 2020, 30, 2003890 

  20. Yanrong Xue, Zhongbin Zhuang*, et al. Sulfate-Functionalized RuFeOx as Highly Efficient Oxygen Evolution Reaction Electrocatalyst in Acid. Adv. Funct. Mater. 2021, 31, 2101405

  21. Hong Guo*, et al. Cooperative catalytic interface accelerates redox kinetics of sulfur species for high-performance Li-S batteries. Energy Storage Materials. 2021, 40, 139-149

  22. Bin Zhang*, et al. Promoting nitric oxide electroreduction to ammonia over electron-rich Cu modulated by Ru doping. SCIENCE CHINA Chemistry. 2021, 64, 1493–1497

  23. Yang Peng*, et al. Geometric Modulation of Local CO Flux in Ag@Cu2O Nanoreactors for Steering the CO2RR pathway toward High-Efficacy Methane Production. Adv. Mater. 2021, 33, 2101741

  24. Yonggang Wang*, et al. Molecular Tailoring of n/p-type Phenothiazine Organic Scaffold for Zinc Batteries. Angew. Chem. Int. Ed. 2021, 60, 20826-20832 

  25. Hongliang Jiang*, Chunzhong Li*, et al. Dynamically Formed Surfactant Assembly at the Electrified Electrode–Electrolyte Interface Boosting CO2 Electroreduction. J. Am. Chem. Soc. 2022, 144, 6613–6622

  26. Yang Peng*, et al. Au-activated N motifs in non-coherent cupric porphyrin metal organic frameworks for promoting and stabilizing ethylene production. Nat. Commun. 2022, 13, 63 

  27. Jie Zeng*, et al. Copper-catalysed exclusive CO2 to pure formic acid conversion via single-atom alloying. Nature Nanotechnology. 2021, 16, 1386-1393 

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  29. Chen Feng, Shiming Zhou*, Jie Zeng*, et al. Tuning the Electronic and Steric Interaction at the Atomic Interface for Enhanced Oxygen Evolution. J. Am. Chem. Soc. 2022, 144,21,9271-9279 

  30. Rui Lin, Jianhui Wang, et al. Asymmetric donor-acceptor moleculeregulated core-shell-solvation electrolyte for high-voltage aqueous batteries. Joule 2022, 6, 399–417 

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  34. Fei Ai, Yijun Lu*, et al. Heteropoly acid negolytes for high-power-density aqueous redox flow batteries at low temperatures. Nature Energy 2022, 7, 417–426 

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  37. Tieliang Li, Yifu Yu, Bin Zhang*, et al. Sulfate-Enabled Nitrate Synthesis from Nitrogen Electrooxidation on Rhodium Electrocatalyst. Angew. Chem. Int. Ed. 2022, e202204541 

  38. Yanbo Li, Bin Zhang, Yifu Yu*, et al. Electrocatalytic Reduction of Low-Concentration Nitric Oxide into Ammonia over Ru Nanosheets. ACS Energy Letters 2022, 7, 1187-1194 

  39. Yanmei Huang, Yifu Yu, Bin Zhang*, et al. Direct Electrosynthesis of Urea from Carbon Dioxide and Nitric Oxide. ACS Energy Letters 2022, 7, 284-291

  40. Wenfu Xie, Hao Li, Min Wei*, et al. NiSn Atomic Pair on Integrated Electrode for Synergistic Electrocatalytic CO2 Reduction. Angew. Chem. Int. Ed. 2021, 60, 7382–7388

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  42. Tiliang Li, Yuting Wang, Yifu Yu*, Bin Zhang*, et al. Ru-Doped Pd Nanoparticles for Nitrogen Electrooxidation to Nitrate. ACS Catal. 2021, 11, 14032-14037

  43. Bin Zhang*, et al. Promoting selective electroreduction of nitrates to ammonia over electron-deficient Co modulated by rectifying Schottky contacts. Science China Chemistry 2020, 63, 1469-1476

  44. Jiangwei Shi, Bin Zhang*, et al. Promoting nitric oxide electroreduction to ammonia over electron-rich Cu modulated by Ru doping. Science China Chemistry 2021, 64, 1493-1497 

  45. Jintao Zhang* et al. Atomic Bridging Structure of Nickel-Nitrogen-Carbon for Highly Efficient Electrocatalytic Reduction of CO2. Angew. Chem.Int. Ed. 2022, 61, e202113918

  46. Lang Xu* et al. Gadolinium Changes the Local Electron Densities of Nickel 3d Orbitals for Efficient Electrocatalytic CO2 Reduction. Angew. Chem.Int. Ed. 2022, 61, e202201166

  47. Bin Zhang* et al. Phenanthrenequinone-like moiety functionalized carbon for electrocatalytic acidic oxygen evolution. Chem. 2022, 8, 1415-1426

  48. Sheng Dai*, Minghui Zhua*, Yifan Han* et al. Probing the role of surface hydroxyls for Bi, Sn and In catalysts during CO2 Reduction. Applied Catalysis B: Environmental 2021, 298,

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